Photochemical formation of azodyes in solutions and films containing azenes and azocomponent

L.M.Bugayova, P.O.Kondratenko


Institute of Physics of National Academy of Sciences of Ukraine, 46 Prospect Ave., 252022 Kyiv, Ukraine

The experimental researches of photochemical azodye derivation in solutions and films containing azene (pentazene or triazene) and azocompound have shown that the photochemical processes take place in associates of the different structure derivated by indicated components. The association of components is stipulated by interaction between completely filled azenes n-MO and unfilled n-MO of azocompounds molecule formed after the sp2 De > sp3-rehybridization of its active point and consequent reexcitation of a molecule. The photochemical process represents intraassociates photoregrouping of links with derivation of azodye molecules and methylamine.

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