Polymodal Snoek relaxation in ageing Fe-C-AE alloys

B.M.Darinsky*, N.Ya.Rokhmanov, V.M.Andronov


V.Karazin Kharkiv National University, 4 Svobody Sq., 61077 Kharkiv, Ukraine *Voronezh State Technical University, 14 Moskovsky Ave., 394026 Voronezh, Russia

Received February 15, 1999

The mechanical relaxation spectrum of low-alloyed Fe-C-AE bcc solid solutions has been studied (AE are substitution alloying elements, namely, Mo, Mn, Si) in the temperature range of carbon relaxation. The measurements were made both for homogeneous (quenched) interstitial-substitution solid solution and after decay of the supersaturated interstitial solid solution during isothermal ageing. Partial modes of Snoek relaxation have been separated. The number of those modes is shown to be equal to that of the substitution solid solution components in the state of low-alloyed interstitial-substitution solid solution. In the alloy where the decay is of continuous type (Fe-Si-C, Si = 0.9% by mass), the displacement of the complex carbon maximum towards higher temperatures has been revealed due to increased thermal stability of its high-temperature mode associated with the C atoms diffusion under stress near two-atomic Si clusters.

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