Funct. Mater. 2013; 20 (3): 279-283.

http://dx.doi.org/10.15407/fm20.03.279

Formation and luminescent properties of MeBr2—Eu  (Me  =Sr  , Ba  ) microcrystals dispersed in NaBr  matrix

A.S.Pushak[1], V.V. Vistovskyy[2], A.Kotlov[3], Z.A.Khapko[2], A.P.Vas'kiv[2], A.V.Gektin[4], A.S.Voloshinovskii[2]

[1]Ukrainian Academy of Printing, 19 Pidgolosko St., 79020 Lviv, Ukraine
[2]I.Franko National University of Lviv, 8 Kyryla i Mefodiya St., 79005 Lviv, Ukraine
[3]HASYLAB at DESY, 85 Notkestraβe, 22607 Hamburg, Germany
[4]Institute for Scintillation Materials, STC "Institute for Single Crystals", National Academy of Sciences of Ukraine, 60 Lenin Ave., 61001 Kharkiv, Ukraine

Abstract: 

The formation of europium doped MeBr2 microcrystals Me  =Sr  , Ba  ) embedded in NaBr  matrix is revealed in NaBr—MeBr2—Eu  crystalline system. The spectral-luminescent properties of embedded MeBr2—Eu  microcrystals are studied upon the synchrotron radiation excitation. The mechanisms of luminescence excitation of europium centers in NaBr—MeBr2—Eu  crystalline system and features of Me2+ and Eu2+ impurity ions aggregation processes in NaBr  matrix are discussed.

References: 

1.N.Cherepy, G.Hull, A.Drobshoff et al., Appl.Phys.Lett., 92, 083508 (2008). http://dx.doi.org/10.1063/1.2885728 http://dx.doi.org/10.1063/1.2885728

2.N.Cherepy, S.Payne, S.Asztalos et al., IEEE Trans.Nucl.Sci., 56, 873 (2009). http://dx.doi.org/10.1109/TNS.2009.2020165 http://dx.doi.org/10.1109/TNS.2009.2020165

3.van E.V.Loef, C.Wilson, N.Cherepy et al., IEEE Trans.Nucl.Sci., 56, 869 (2009). http://dx.doi.org/10.1109/TNS.2009.2013947 http://dx.doi.org/10.1109/TNS.2009.2013947

4.E.D.Bourret-Courchesne, G.Bizarri, S.M.Hanrahan et al., Nucl. Instr. Meth. Phys. Res. A, 613, 95 (2010). http://dx.doi.org/10.1016/j.nima.2009.11.036 http://dx.doi.org/10.1016/j.nima.2009.11.036

5.J.Selling, S.Schweizer, M.Birowosuto et al., IEEE Trans.Nucl.Sci., 55, 1183 (2008). http://dx.doi.org/10.1109/TNS.2008.922825 http://dx.doi.org/10.1109/TNS.2008.922825

6.M.Globus, B.Grinyov, J.Kim, Inorganic Scintillators for Modern and Traditional Applications, Institute for Single Crystals, Kharkiv (2005) [in Ukrainian].

7.A.Voloshinovskii, A.Gloskovsky, S.Zazubovich et al., Phys.Stat.Sol.(b), 225, 257 (2001). http://dx.doi.org/10.1002/(SICI)1521-3951(200105)225:1<257::AID-PSSB257>3.0.CO;2-H http://dx.doi.org/10.1002/(SICI)1521-3951(200105)225:1<257::AID-PSSB257>3.0.CO;2-H

8.A.Pushak, V.Vistovskyy, S.Myagkota et al., Functional Materials, 17, 294 (2010).

9.A.Pushak, P.Savchyn, V.Vistovskyy et al., J.Luminescence, 135, 1 (2013). http://dx.doi.org/10.1016/j.jlumin.2012.10.008 http://dx.doi.org/10.1016/j.jlumin.2012.10.008

10.V.Vistovskyy, P.Savchyn, G.Stryganyuk et al., J.Phys.:Condens.Matter., 20, 325218 (2008). http://dx.doi.org/10.1088/0953-8984/20/32/325218 http://dx.doi.org/10.1088/0953-8984/20/32/325218

11.V.Vistovskii, A.Pushak, S.Myagkota et al., Opt. and Spectr.., 109, 352 (2010). http://dx.doi.org/10.1134/S0030400X10090079 http://dx.doi.org/10.1134/S0030400X10090079

12.P.Savchyn, V.Vistovskyy, A.Pushak et al., Nucl. Instr. Meth. Phys. Res. B, 274, 78 (2012). http://dx.doi.org/10.1016/j.nimb.2011.11.024 http://dx.doi.org/10.1016/j.nimb.2011.11.024

13.A.Voloshinovskii, G.Stryganyuk, G.Zimmerer et al., Phys.Stat.Sol.(a), 202, R101 (2005). http://dx.doi.org/10.1002/pssa.200521011 http://dx.doi.org/10.1002/pssa.200521011

14.E.V.D.van Loef, P.Dorenbos, C.W.E.van Eijk et al., Appl.Phys.Lett., 77, 1467 (2000). http://dx.doi.org/10.1063/1.1308053 http://dx.doi.org/10.1063/1.1308053

15.P.Dorenbos, E.V.D. van Loef, A.Vink et al., J.Luminescence, 117, 147 (2006). http://dx.doi.org/10.1016/j.jlumin.2005.04.016 http://dx.doi.org/10.1016/j.jlumin.2005.04.016

16.A.Vasil'ev, I.Iskandarova, A.Scherbinin et al., J.Luminescence, 129, 1555 (2009). http://dx.doi.org/10.1016/j.jlumin.2009.04.041 http://dx.doi.org/10.1016/j.jlumin.2009.04.041

17.G.Zimmerer, Radiat.Meas., 42, 859 (2007). http://dx.doi.org/10.1016/j.radmeas.2007.02.050 http://dx.doi.org/10.1016/j.radmeas.2007.02.050

18.J.Garcia-Sole, M.Aguilar, F.Agullo-Lopez et al., Phys.Rev.B, 26, 3320 (1982). http://dx.doi.org/10.1103/PhysRevB.26.3320 http://dx.doi.org/10.1103/PhysRevB.26.3320

19.Th.Troster, S.Schweizer, M.Secu et al., J.Luminescence, 99, 343 (2002). http://dx.doi.org/10.1016/S0022-2313(02)00371-X http://dx.doi.org/10.1016/S0022-2313(02)00371-X

20.S.Myagkota, G.Stryganyuk, A.Voloshinovskii et al., Opt. Commun., 229, 271 (2004). http://dx.doi.org/10.1016/j.optcom.2003.10.036 http://dx.doi.org/10.1016/j.optcom.2003.10.036

21.F.Lopez, H.Murrieta, J.Hernandez et al., J.Luminescence, 26, 129 (1981). http://dx.doi.org/10.1016/0022-2313(81)90175-7 http://dx.doi.org/10.1016/0022-2313(81)90175-7

22.G.Stryganyuk, P.Savchyn, V.Vistovskyy et al., Phys.Stat.Sol.(a), 206, 147 (2009). http://dx.doi.org/10.1002/pssa.200824304 http://dx.doi.org/10.1002/pssa.200824304

23.P.Savchyn, S.Myagkota, A.Voloshinovskii et al., Radiat.Meas., 42, 697 (2007). http://dx.doi.org/10.1016/j.radmeas.2007.01.069 http://dx.doi.org/10.1016/j.radmeas.2007.01.069

Current number: