Funct. Mater. 2014; 21 (3): 333-337.

http://dx.doi.org/10.15407/fm21.03.333

Synthesis of Na+,CO32--containing calcium phosphate nanoparticles and their thermal transformations

A.I.Malyshenko[1], N.Yu.Strutynska[1], I.V.Zatovsky[1], N.S.Slobodyanik[1], M.Epple[2], O.Prymak[2]

[1] T. Shevchenko National University of Kyiv, 64/13 Volodymyrska Str., 01601 Kyiv, Ukraine
[2] Inorganic Chemistry and Center for Nanointegration Duisburg-Essen (CeNIDE), University of Duisburg-Essen, Universitaetsstrasse, 5-7, 45117 Essen, Germany

Abstract: 

The nanoparticles of Na+,CO32--containing hydroxyapatites have been prepared from aqueous solutions for system Na+-Ca2+-NO3--CO32--PO43- at molar ratio of Ca/P = 1.67:1 and CO32-/PO43- = 0, 1.0, 2.0, 3.0. Thermal transformations of the obtained phosphates have been established for the temperature range of 80-900°C. The obtained complex-substituted HAP have been investigated using IR spectroscopy, scanning electron microscopy, X-ray diffraction and thermogravimetry.

Full text in PDF

References: 

1. S.V.Dorozhkin, J. Mater. Sci., 42, 1061 (2007). http://dx.doi.org/10.1007/s10853-006-1467-8

2. RZ.LeGeros, Calcium Phosphates in Oral Biology and Medicine, in: Rz.LeGeros, Monographs in Oral Sciences, ed. by H.M.Myers, Basel (1991), v.15, p.37. http://dx.doi.org/10.1159/issn.0077-0892

3. V.V. Nosenko, I.P.Vorona, S.S.Ishchenko et al., Radiat. Measur, 47, 970 (2012). http://dx.doi.org/10.1016/j.radmeas.2012.08.008

4. T.V.Safronova, S.A.Korneychuk, V.I.Putlyaev, V.A.Krutko, Glass and Ceramics, No.1, 30 (2012). http://dx.doi.org/10.1007/s10717-012-9409-1

5. J.A.M.Zahedi, F.Ziaie, M.M.Larijani et al., Indian J. Sci. Technol., 5, No.23, 2464 (2012).

6. K.Matsunaga, H.Murata, Mater. Trans., 50, 1041 (2009). http://dx.doi.org/10.2320/matertrans.MC200819

7. C.H.Suelter, Science, 168, 789 (1970). http://dx.doi.org/10.1126/science.168.3933.789

8. F.Ginty, A.Flynn, K.D.Cashman, Br. J. Nutr., 79, 343 (1998). http://dx.doi.org/10.1079/BJN19980058

9. F.C.M.Driessens, Inorg. Chim. Acta, 80, 19 (1983). http://dx.doi.org/10.1016/S0020-1693(00)91256-8

10. E.A.P.Maeyer, R.M.H.Verbeeck, D.E.Naessens, Inorg. Chem., 32, 5709 (1993). http://dx.doi.org/10.1021/ic00077a011

11. I.P.Vorona, S.S.Ishchenko, N.P.Baran et al., Solid State Phys., 55, 2417 (2013). http://dx.doi.org/10.1134/S1063783413120329

12. A.Porter, N.Patel, R.Brooks et al., J. Mater. Sci: Mater. in Medicine, 16, 899 (2005). http://dx.doi.org/10.1007/s10856-005-4424-1

13. J.-P.Lafon, E.Champion, D.Bernache-Assolliant et al., J. Thermal Anal. Colametry, 72, 1127 (2003). http://dx.doi.org/10.1023/A:1025036214044

Current number: