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Funct. Mater. 2017; 24 (3): 393-399.

doi:https://doi.org/10.15407/fm24.03.393

GdVO4:Eu3+ nanoparticles - embedded CaCO3 microspheres: synthesis and characterization

I.I.Bespalova1, S.L.Yefimova1, T.N.Tkacheva1, K.A.Hubenko, A.V.Sorokin1, P.V.Mateychenko2

1Institute for Scintillation Materials, STC "Institute for Single Crystals", National Academy of Sciences of Ukraine, 60 Nauky Ave., 61072 Kharkiv, Ukraine
2Institute for Single Crystals, STC "Institute for Single Crystals",National Academy of Sciences of Ukraine, 60 Nauky Ave., 61072 Kharkiv, Ukraine

Abstract: 

In present study, we report on synthesis of fluorescent GdVO4:Eu3+ nanoparticle-embedded CaCO3 microparticles (CaCO3@GdVO4:Eu3+) and their characterization. Synthesized CaCO3@GdVO4:Eu3+ microspheres are of vaterite polymorph and about 2 <$E mu>m diameter with -12.80±0.82 mV zeta potential. The specific surface area of the CaCO3@GdVO4:Eu3+ microspheres and pore size distribution were analyzed by Brunauer-Emmett-Teller method. The microparticles was classified as macroporous ones with a wide distribution of pore sizes.The specific surface area for CaCO3@GdVO4:Eu3+ microspheres (SBET = 25.2 m2/g) is higher than reported for CaCO3 microparticles obtained without any additives. CaCO3@GdVO4:Eu3+ microspheres exhibit strong fluorescence both in a water solution and under fluorescent microscopy conditions that makes them attractive for bio-related application.

Keywords: 
nanoparticles, microspheres, luminescence, porosity, specific surface area.
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