Funct. Mater. 2017; 24 (4): 521-526.
Influence the cationic substitution in AgGaGe3Se8 on the electro-optical, IR optical and nonlinear properties
1Department of Solid State Physics, Lesya Ukrainka Eastern European National University, 13 Voli Ave., 43025 Lutsk, Ukraine
2Department of Inorganic and Physical Chemistry, Lesya Ukrainka Eastern European National University, 13 Voli Ave., 43025 Lutsk, Ukraine
3Faculty of Electrical Engineering, Czestochowa Univerisity technology, 17 Armii Krajowej Czestochowa, Poland
4 Institute of Physics, J.Dlugosh Academy, Armii Krajowej 13/15, PL-42-201, Czestochowa, Poland
In present article we present results of detailed study of the possibility adapting AgGaGe3Se8 single crystal properties to desired requirements by investigate the influence of the different cationic substitution on the physical properties: optical, nonlinear optical (NLO) - Second Harmonic Generation (SHG) and temperature dependent photoconductivity. We report results obtained for modified crystals based on AgGaGe3Se8 by cationic substitution of the elements belong to first - (Ag-Cu), third (Ga-In), and fourth (Ge-Sn) groups of the periodic system. For the convincing observation the effects of various impurities and compare results with obtained for virgin AgGaGe3Se8 crystal was conducted replacing at 5 mol. % one element by another.
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