Funct. Mater. 2021; 28 (2): 266-274.
doi:https://doi.org/10.15407/fm28.02.266
Transfer processes in an equiatomic FeNi composite obtained by electroconsolidation
1V. Karazin Kharkiv National University, 4 Svobody Sq., 61022 Kharkiv, Ukraine 2Ukrainian State University of Railway Transport, 7 Feierbakh Sq., 61050 Kharkiv, Ukraine 3Centre of Low Temperature Physics, Faculty of Science, P. Safarik University, 9 Park Angelinum, 04154 Kosice, Slovakia
Abstract:
The paper presents studying by resistive and energy-dispersive methods the transfer processes in a binary Fe-Ni system obtained by the method of electroconsolidation (SPS technology). Well-separated regions of almost pure iron and nickel were found. The concentration dependence of interdiffusion in the composite under study passes through a maximum at a nickel concentration of ~ 70 at. %. It is shown that the value of the interdiffusion coefficient of the electroconsolidated Fe-Ni composite is significantly higher than that of an alloy of similar composition, which is probably the result of the effect of the SPS technology, as well as an increase in the contribution of intergranular diffusion. It was found that the electrical and thermal conductivity of an electroconsolidated sample is significantly higher than that of samples of the same composition obtained by melting. It was found that the temperature dependences of the resistivity of the electroconsolidated sample in the investigated range of 5-300 K are due to the scattering of electrons by defects and phonons, and the scattering of electrons by phonons can be approximated with a high accuracy by the Bloch-Gruneisen-Wilson relation.
Keywords:
electroconsolidation, interdiffusion, electrical conductivity, thermal conductivity, electrons, phonons, scattering, energy-dispersive methods.
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