Funct. Mater. 2021; 28 (2): 394-402.

doi:https://doi.org/10.15407/fm28.02.394

Investigation of superhigh-frequency treatment influence on structuring of epoxy composites by infrared- and electron paramagnetic resonance spectroscopy analyses

P.D.Stukhlyak, O.S.Holotenko, R.Z.Zolotyi, A.G Mykytyshyn

Department of Computer - Integrated Technologies, Ternopil I.Puluj National Technical University, 56 Ruska Str., 46001 Ternopil, Ukraine

Abstract: 

The regularities of the rate of physical-chemical processes during the formation of epoxy binder are determined. Infrared (IR) and electron paramagnetic resonance spectral analyses of epoxy composites filled with dispersed particles and modified by superhigh-frequency electromagnetic field were carried out. The mechanism of interaction of the matrix with filler particles of different dispersion and nature has been substantiated.

Keywords: 
epoxy composite, interaction mechanism, IR spectral analysis, structure, disperse filler, polyethylene polyamine.
References: 
1. V.A.Pakharenko, Reinforced Thermoplastics, Technika, Kyiv (1986).
 
2. I.D.Simonov-Yemelyanov, V.N.Kulyeznyev, Fundamentals of Composite Materials Creation, MIHM, Moscow (1986) [in Russian].
 
3. V.P.Solomko, Filled Crystallizing Polymers, Naukova Dumka, Kyiv (1986).
 
4. S.G.Kalganova, Electrotechnology of Non-thermal Modification of Polymer Materials in SHF Electromagnetic Field: Extended Abstract of Doctor of Sciences (2009).
 
5. N.Ya.Feldman, Modern Electronics, 5, 64 (2009).
 
6. P.Stukhlyak, O.Holotenko, O.Skorokhod, East-Europ. J. Adv. Techn., 1, 32 (2015).
 
7. A.Buketov, P.Maruschak, O.Sapronov et al., Mol. Cryst. Liq. Cryst., 628, 167 (2016).
https://doi.org/10.1080/15421406.2015.1137122
 
8. L.A.Kazitsyna, N.B.Kupletskaya. Application of UV-, IR- and NMR-spectroscopy in Organic Chemistry: textbook. Manual [for HEE], Vysshaya Shkola, Moscow (1971) [in Russian].
 
9. L.Sperling, Interpenetrating: Polymer Networks and Similar Materials. Mir, Moscow (1984) [in Russian].
https://doi.org/10.1007/978-1-4899-1831-4_1
 
10. P.D.Stukhlyak, Epoxy Composites for Shield Protection, Zbruch, Ternopil (1994).
 
11. A.V.Buketov, P.D.Stukhlyak, Y.M.Kalba, Physico-chemical Processes in the Formation of Epoxy Composite Materials, Zbruch, Ternopil (2005).
 
12. P.D.Stukhlyak, O.S.Holotenko et al., Phys.-Chem. Mechan. Mater., 51/2, 59 (2015).
https://doi.org/10.1007/s11003-015-9830-z

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