Funct. Mater. 2021; 28 (3): 580-586.

doi:https://doi.org/10.15407/fm28.03.580

Structure and antibacterial property of coordination polymer [Ni2(en)4Cl2]Cl2

Yanan Luo1, Miao Kong2, Pengfei Wang1, Kangming Liu1, Zhengyu Yang1, Yutong Wang1

1College of Pharmacy, Jilin Medical University, 5 Jilin Str., 132013 Jilin, P. R. China
2College of Chemical and Pharmaceutical Engineering, Jilin Institute of Chemical Technology, 45 Chengde Str., 132022 Jilin, P. R. China

Abstract: 

Complex [Ni2(en)4Cl2]ClV2 (1) was synthesized for the first time through solvothermal synthesis by ethylenediamine (en) and Ni(II) ion. Complex 1 exhibits a zero-dimensional (0D) structure, which is linked into a three-dimensional (3D) supramolecular network through hydrogen bonds N-H·Cl. Moreover, the antibacterial property of complex 1 was tested. The antibacterial properties against Gram-negative bacteria are slightly better than against Gram-positive bacteria in complex 1.

Keywords: 
hydrogen bond; supramolecular structure; antibacterial property.

Full text in PDF

References: 
1. J.F.Wang, X.Xu, R.N.Bian et al., Inorg. Chim. Acta, 516, 120095 (2020).
https://doi.org/10.1016/j.ica.2020.120095
 
2. H.Aasif, F.Mohammed, A.M.Eyasin et al., J. CO2 Util., 50, 101603 (2021).
https://doi.org/10.1016/j.jcou.2021.101603
 
3. L.Qin, Q.Hu Q, Y.P.Zou et al., Micropor. Mesopor. Mat., 312, 110813 (2021).
https://doi.org/10.1016/j.micromeso.2020.110813
 
4. M.Abedi, G.Mahmoudi, P.Hayati et al., New J. Chem., 43, 17457 (2019).
https://doi.org/10.1039/C9NJ04382A
 
5. J.Yan, L.Wilbraham, P.N.Basa et al., Inorg. Chem., 57, 15009 (2018).
https://doi.org/10.1021/acs.inorgchem.8b02845
 
6. V.Thottempudi, H.X.Gao, J.M.Shreeve, J. Am. Chem. Soc., 133, 6464 (2011).
https://doi.org/10.1021/ja2013455
 
7. Y.Tao, C.Yang, H.Fang et al., Cryst. Growth Des., 19, 3358 (2019).
https://doi.org/10.1021/acs.cgd.9b00252
 
8. S.T.Hafeez, S.Ali, M.N.Tahir et al., J. Coord. Chem., 67, 2479 (2014).
https://doi.org/10.1080/00958972.2014.940922
 
9. Y.N.Luo, X.Z.Xu, F.X.Sun et al., Chem. Res. Chin. Univ., 30, 27 (2014).
https://doi.org/10.1007/s40242-013-3236-y
 
10. J.Wang, Z.J.Ji, Z.H.Shui et al., Mater. Rev., 27, 4 (2013).
 
11. L.He, Z.Li, C.Guo et al., Sensor. Act. B-Chem., 298, 126852 (2019).
https://doi.org/10.1016/j.snb.2019.126852
 
12. X.R.Su, Y.Y.Xue, Q.Li, Chin. J. Burns, 34, 183 (2018).
 
13. H.Hu, D,Zhang, H.Liu et al., Chin. Chem. Lett., 32, 577 (2021).
https://doi.org/10.1016/j.cclet.2020.03.071
 
14. R.Begum, M.Rehman, K.Shahid et al., J. Mol. Struct., 1242, 130801 (2021).
https://doi.org/10.1016/j.molstruc.2021.130801
 
15. O.V.Dolomanov, L.J.Bourhis, R.J.Gildea et al., J. Appl. Crystallogr., 42, 339 (2009).
https://doi.org/10.1107/S0021889808042726
 
16. G.M.Sheldrick. SHELXTL NT Crystal Structure Analysis Package[CP]. Version 5.10; Bruker AXS, Analytical X-ray System: Madison, WI, 1999.
 
17. X.J.Duan, X.D.Du, B.B.Zhang et al., Biomed. Engin. Clin. Med., 19, 237 (2015).

Current number: