Funct. Mater. 2021; 28 (4): 810-818

doi:https://doi.org/10.15407/fm28.04.810

Influence of environmental factors on functional properties of optical polymer films

A.Dunaieva, D.Mishurov, A.Voronkin, O.Nedilko, A.Roshal

1National Technical University Kharkiv Polytechnic Institute Frunze str., 21, 61002, Kharkiv, Ukraine
2Institute of Chemistry at V.N. Karazin Kharkiv National University Svoboda sqr., 4, 61022, Kharkiv, Ukraine
3V.N. Karazin Kharkiv National University Svoboda sqr., 4, 61022, Kharkiv, Ukraine

Abstract: 

The paper is devoted to investigation of exploitation properties of optical film materials based on cross-linked polymers containing flavonoid fragments, namely 3,7,5,3',4'-pentahydroxyflavone (quercetin) and 3,7,5,3',4'-pentahydroxyflavone-8-sulphonic acid (sulfoquercetin) built into the polymer chains. The photoinduced destruction, fungal resistance and adhesion properties of these polymer materials were investigated. The photostability of polymer films was estimated using electronic absorption spectroscopy. Fungal resistance and fungistatic effect were tested using mold fungi species Aspergillus niger and Penicillum chrysogenum according to standard methods described in ISO 846-1997. Adhesion ability was determined according to ISO 2409. All the determined exploitation characteristics of the polymer films studied demonstrate the a very high functional level: a high photostability and fungal resistance, a substantial fungistatic effect and a high adhesion level, which confirms the prospects of using the flavonoid-containing polymers for preparation of optical films for applications in photonics purposes.

Keywords: 
Cross-linked polymers; optical polymer films; exploitation properties; photostability; fungal stability, adhesion ability
References: 

 

1. D.Avci, A.Basoglu, Y.Atalay, Struct. Chem., 21, 213 (2010).
https://doi.org/10.1007/s11224-009-9566-1
 
2. M.Medved, S.Budzak, I.Cernusak, J. Mol. Struct. (Theochem), 961, 66 (2010).
https://doi.org/10.1016/j.theochem.2010.09.001
 
3. W.Bartkowiak, K.Strasburger, J. Mol. Struct. (Theochem), 960, 93 (2010).
https://doi.org/10.1016/j.theochem.2010.08.028
 
4. L.A.D.Souza, A.M.D.Silva, G.M.A.Junqueira, at al., J. Mol. Struct. (Theochem), 959, 92 (2010).
https://doi.org/10.1016/j.theochem.2010.08.018
 
5. D.Mishurov, A.Voronkin, S.Bogatyrenko, J. Polymer Mater. Int. J., 35, (2018).
 
6. J.Liu, G.Xu, F.Liu, at al., RSC Adv., 5, 15784 (2015).
https://doi.org/10.1039/C4RA13250E
 
7. F.Castet, V.Rodriguez, J.Pozo, at al., Acc. Chem. Res., 46, 2656 (2013).
https://doi.org/10.1021/ar4000955
 
8. T.Constant, S.Hornett, D.Chang, at al., Nature Phys., 12, 124 (2016).
https://doi.org/10.1038/nphys3545
 
9. M.Humar, S.H.Yun, Nat. Photonics, 9, 572 (2015).
https://doi.org/10.1038/nphoton.2015.129
 
10. H.Aoki, K.Ishikawa, H.Takezoe, at al., Jpn. J. Appl. Phys., 35, 168 (1996).
https://doi.org/10.1143/JJAP.35.168
 
11. M.Suslin, O.Nedilko, D.Mishurov, International Biodeterioration & Biodegradation, 110, 136 (2016),.
https://doi.org/10.1016/j.ibiod.2016.03.021
 
12. B.N.Balzer, S.Micciulla, S.Dodoo, at al., ACS Appl. Mater. Interfaces, 5, 6300 (2013),.
https://doi.org/10.1021/am4013424
 
13. I. J. Zvonkina, Adhesion of polymer coatings: Principles and evaluation, in: Hosseini M., Makhlouf A. (eds) Industrial Applications for intelligent polymers and coatings, Springer, Cham, (2016)
https://doi.org/10.1007/978-3-319-26893-4_28
 
14. D.Mishurov, Chem. Chem. Technol., 13, 33 (2019).
https://doi.org/10.23939/chcht13.01.033
 
15. D.Mishurov, A.Voronrin, A.Roshal, Struct. Chem., 27, 285 (2016).
https://doi.org/10.1007/s11224-015-0694-5
 
16. D.Mishurov, A.Voronkin, O.Nedilko, I.Zykina, Polymer Testing., 87, 106535 (2020).
https://doi.org/10.1016/j.polymertesting.2020.106535
 
17. Doroshenko A.O. (1999) Spectral Data Lab software, Kharkiv.
 
18. International Standardization Organization, 1997. ISO 846:1997. Plastics -evaluation of the Action of Microorganisms, 22 pp.
 
19. ISO 2409: 1992. Paints and varnishes. Cross-cut test. 1992. P. 1-8.
 
20 H.Guo, L.Liu, X.Hao, at al., Optic Laser Tech., 7, 1184 (2011).
https://doi.org/10.1016/j.optlastec.2011.03.006
 
21 S.Dall'Acqua, G.Miolo, G.Innocenti, at al., Molecules., 17, 8898 (2012).
https://doi.org/10.3390/molecules17088898
 
22 T.Cushnie, A.Lamb, International Journal of Antimicrobial Agents., 26, 343 (2005)
https://doi.org/10.1016/j.ijantimicag.2005.09.002
 

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