Funct. Mater. 2024; 31 (1): 119-127.

doi:https://doi.org/10.15407/fm31.01.119

Q-factor of plasmonic resonances and field enhancement in the vicinity of spherical metallic nanoparticles

A.V. Korotun^1,2, H.V. Moroz¹, R.Yu. Korolkov¹

¹ National University Zaporizhzhia Polytechnic б, 64 Zhukovsky Str., Zaporizhzhia, 69063, Ukraine
² G.V. Kurdyumov Institute for Metal Physics of National Academy of Sciences of Ukraine, 36 Academician Vernadsky Blvd., Kyiv, 03142, Ukraine

Abstract:

This work investigates the optical response of spherical metal nanoparticles under scattering and absorption conditions, as well as the field enhancement in the vicinity of the nanoparticles due to the excitation of surface plasmon resonance. Relations are obtained to determine the frequency dependence of the field enhancement and the size and frequency dependence of Q-factor, taking into account all relaxation mechanisms. The radii of spherical particles of different metals, at which the surface and radiation relaxations make the same contribution into the effective relaxation rate, as well as the radii at which the effective relaxation rate will be minimal, have been estimated. It has been shown that a decrease in the linewidth of the surface plasmon resonance leads to an increase both in Q-factor and in the magnitude of the field enhancement in the vicinity of nanoparticles..

Keywords:

spherical metallic nanoparticle, surface plasmonic resonance, Q-factor, field enhancement, effective relaxation rate, Drude model.

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