Funct. Mater. 2024; 31 (1): 128-139.

doi:https://doi.org/10.15407/fm31.01.128

Formation of multifunctional perovskite-like layered oxide materials using precursors based on coordinated nitrates of alkali and rare-earth metals

O.G. Dryuchko, V.V. Soloviev, N.V. Bunyakina, B.R. Boriak, O.E. Illiash

National University "Yuri Kondratyuk Poltava Polytechnic", 24 Pershotravnevy prospect, 36011, Poltava, Ukraine

Abstract: 

The results of the research summarize important information about alkaline coordination nitrates of rare earth elements of the cerium subgroup. They are used as precursors for promising modern multifunctional materials. Using a complex of physicochemical methods, the conditions of their formation and existence, the nature of chemical bonding, composition, structure, coordination polyhedra Ln, and ligand coordination type have been elucidated. The existence of a few isotypic series has been revealed based on the stoichiometry of the composition, structure, and characteristic properties. The obtained primary information is the basis for detecting, identifying, and controlling the phase state of processing objects in preparatory stages. It is important at the stages of forming transformational technological schemes, selecting criteria for the compatibility of constituent ingredients, and clarifying the stages and conditions for their implementation. The range of innovative applications includes the formation of monolayer and layered nanostructured oxide compositions of lanthanides and transition elements with catalytic and photocatalytic activity, as well as self-cleaning coatings with hydrophilic properties. The proposed methods include various combined activation of the processes under study and controlled changes in the properties of the resulting target products. The established technological-functional dependencies were assessed. To enhance the photocatalytic activity of coatings based on highly dispersed anatase TiO2, a technique has been proposed for the chemical modification of oxidation centers in their surface layer, which involves heat treatment in contact with the melt of alkaline coordination lanthanide nitrates. An effective photocatalytic decomposition of organic substrate vapors is shown using ethanol as an example.

Keywords: 
alkaline coordination nitrates of lanthanides, formation conditions, crystal structure of compounds, characteristic properties, transformations with physical activation

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