Funct. Mater. 2021; 28 (3): 481-485.

doi:https://doi.org/10.15407/fm28.03.481

Obtaining tin (II) oxide by a chemical method

Perdinan Sinuhaji1, Wahyu Bambang Widayatno2, Agus Sukarto Wismogroho 2, Cherly Firdharini2, Paulina Aryati Samosir1

1Universitas Sumatera Utara, Medan, 20155 Indonesia
2Research Centre of Physics, Indonesia Institute of Sciences, Serpong 15314, Tangerang Selatan, Banten, Indonesia

Abstract: 

Tin (II) oxide formation has been carried out by reacting tin powder with nitric acid at various concentrations (4 M; 4.5 M; 5 M) in a glass beaker under spontaneous stirring at various heating temperatures (100°C; 90°C; 80°C). The resulting sample in the form of a yellowish precipitate was cooled, washed using distilled water and acetone, dried in a mortar and filtered. The samples were iodometrically tested and characterized using differential thermal analysis (DTA), optical microscopy (OM) for morphology and phase analysis (XRD). The results of the iodometric test showed different oxidations. At the 4 M concentration with all heating temperature variations, Sn2+ oxidation was observed. According to the results of OM study, the surface morphology was irregular and there was a residue of tin that did not completely react with nitric acid. The results of the thermal test (DTA) showed that the sample experienced thermal decomposition at temperatures of 419°C and 426°C. XRD results indicate that the formation of SnO2 has occurred.

Keywords: 
tin (II) oxide, SnO<sub>2</sub>, precipitate, morphology.

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